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Updated: Apr 7, 2026

Atomic Scale Structural Studies of Macromolecular Assemblies by Solid-state Nuclear Magnetic Resonance Spectroscopy
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Atomic Scale Structural Studies of Macromolecular Assemblies by Solid-state Nuclear Magnetic Resonance Spectroscopy

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パラフェニレンと"アビラム-ラトナー"ブリッジを用いた σ と π カップリングのコンフォーマショナル・ランドスケープの決定

Daniel E Stasiw1, Jinyuan Zhang1, Guangbin Wang1

  • 1†Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, United States.

Journal of the American Chemical Society
|July 9, 2015
PubMed
まとめ

分子構造がドナー・ブリッジ・アクセプター・システムにおける電子結合にどのように影響するか定量化しました. ブリッジにメチル群を配置すると,分子電子学にとって極めて重要な磁気交換にシグマとパイの軌道の貢献が明らかになった.

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