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A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones
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A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones

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ニッケル/フォトレドックス二重触媒による高地域選択性インドリン合成

Sarah Z Tasker1, Timothy F Jamison1

  • 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.

Journal of the American Chemical Society
|July 22, 2015
PubMed
まとめ

この研究は,ニッケル/フォトレドックス触媒を用いたインドリンの新種の1段階合成を導入する. この方法は,ヨドアセタニリドとアルケンの3代代用製品に対して高い地域選択性を得ます.

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