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Updated: Apr 6, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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イソニトリルとCp* ((Cl) M ((Diene)) (M = Ti, Hf) の反応

Travis N Valadez1, Jack R Norton1, Michelle C Neary1

  • 1Department of Chemistry, Columbia University, New York, New York 10027, United States.

Journal of the American Chemical Society
|August 1, 2015
PubMed
まとめ

タイタンとハフニウムダイエンの複合体は,イソニトリルと反応して新しいダイミンとディアザフラサイクロペンタン構造を形成する. これらの反応は,有機金属化学の新たな経路と複雑な分子再配置を明らかにします.

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