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Synthesis of 1,2-Azaborines and the Preparation of Their Protein Complexes with T4 Lysozyme Mutants
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1,4,2-ディアザボロールの分離と反応性

Bochao Su1, Yongxin Li1, Rakesh Ganguly1

  • 1Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, and ‡NTU-CBC Crystallography Facility, Nanyang Technological University , 637371, Singapore.

Journal of the American Chemical Society
|August 25, 2015
PubMed
まとめ

研究者は新しい1,4,2-ディアザボロール誘導体を合成し,電子移位によってその芳香性を確認した. 反応性研究では,電ophilesとの行動を調査し,ヘテロサイクルの化学に関する知識を広げました.

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Arenediazonium substitution reactions occur when the diazonium group is substituted by various functional groups such as halides, hydroxyl, nitrile, etc. For instance, arenediazonium salts react with copper(I) salts of chloride, bromide, or cyanide to form corresponding aryl chlorides, bromides, and nitriles. These reactions are named Sandmeyer reactions. Although the mechanism of this reaction is complicated, as illustrated in Figure 1, they are believed to progress via an aryl copper...
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