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A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis
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O-H結合は,アルコールのC-アルキル化のためのα-C-H結合からH原子移転を促進する

Jenna L Jeffrey1, Jack A Terrett1, David W C MacMillan2

  • 1Merck Center for Catalysis, Princeton University, Princeton, NJ 08544, USA.

Science (New York, N.Y.)
|August 29, 2015
PubMed
まとめ

この研究では,フォトレドックス触媒と水素原子移転を用いた選択的アルキル化のための新しい触媒方法が詳細に示されています. テトラ-n-ブチラモニウムフォスファートは,特定のアルコールC-H結合の選択性を高めます.

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