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A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis
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イリジウム (III) 触媒によるC−H結合とダイアリオドニウム塩の直接アリレーション

Pan Gao1,2, Wei Guo3, Jingjing Xue1

  • 1State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University , Nanjing 210093, China.

Journal of the American Chemical Society
|September 9, 2015
PubMed
まとめ

新しいイリジウム触媒によるC-Hアリレーション法により,様々な有機分子におけるsp2およびsp3C-H結合の直接結合が可能である. この汎用性の高い合成ツールでは,ダイアリオドニウムトリフラートを使用し,複雑な化合物の合成に幅広い機能群の互換性を提供します.

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