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Updated: Apr 3, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
09:45

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

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エナチオセレクティブのイネ-エノンサイクライゼーションのためのキラルカチオンCp (x) Ru (II) コンプレックス

David Kossler1, Nicolai Cramer1

  • 1Laboratory of Asymmetric Catalysis and Synthesis, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL) , CH-1015 Lausanne, Switzerland.

Journal of the American Chemical Society
|September 17, 2015
PubMed
まとめ

チラルのサイクロペンタディエンリルルテニウム (II) 複合体は,イネ-エノンの循環を効率的に触媒化する. この方法は,不飽和エステルまたはウェインレブアミドからアイリド骨格を生成する高いエナチオ選択性を持つピランを素早く生成します.

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