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調節ニッケルとルイス酸性グループ13のメタロリガンドを触媒オレフィン水素化のために

Ryan C Cammarota1, Connie C Lu1

  • 1Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota , 207 Pleasant Street SE, Minneapolis, Minnesota 55455, United States.

Journal of the American Chemical Society
|September 18, 2015
PubMed
まとめ

グループ13の金属を持つ二金属ニッケル複合体は,オレフィン水素化を触媒とする. より大きな金属イオンはより強い結合を作り,より小さなアルミニウムイオンとは異なり,水素の活性化と触媒を可能にします.

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