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Updated: Apr 3, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
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ディメチル硫化物におけるプロリンエナミンの形成経路の再検討:NMRで決定されたレート定数

Michael H Haindl1, Johnny Hioe1, Ruth M Gschwind1

  • 1Institut für Organische Chemie, Universität Regensburg , D-93053 Regensburg, Germany.

Journal of the American Chemical Society
|September 22, 2015
PubMed
まとめ

この研究はエナミンの形成率を定量化し,DMSOにおける主要な経路としてイミニウム脱プロトネーションを明らかにした. エナミンの形成の動態は,核愛者の強さではなく,実験条件に依存する.

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