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Updated: Apr 3, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Pd(0) - Si-Si と Sn-Sn 結合に触媒化されたカルベンの挿入

Zhenxing Liu1, Haocheng Tan1, Tianren Fu1

  • 1Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University , Beijing 100871, China.

Journal of the American Chemical Society
|September 25, 2015
PubMed
まとめ

この研究は,N-トシルヒドラゾンを用いて,シリコン-シリコンおよびチン-チンの結合にパラジウム触媒カルベンの挿入を初めて導入した. この反応により,温和な条件下では,ジミナルビス・シランおよびビス・スタナン (β-β-β-β-β-β-β-β-β) 誘導体が効率的に生成される.

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