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Updated: Jan 25, 2026

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(4+1) vs (4+2): C-C アクティベーションによるサイクロブタノンと三置換アレン間の触媒内結合

Xuan Zhou1, Guangbin Dong1

  • 1Department of Chemistry, University of Texas at Austin , Austin, Texas 78712, United States.

Journal of the American Chemical Society
|October 7, 2015
PubMed
まとめ

新しいロジウム触媒反応により,単純なサイクロブタノンとアレンから複雑な[4.2.1]-バイサイクル分子が生成される. この方法は,高エナチオ選択性を持つ2つの四次炭素センターを効率的に構築し,多用途の合成経路を提供します.

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