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Updated: Mar 31, 2026

A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones
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A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones

Published on: January 21, 2020

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前例のない形式的な [5 + 2] o-カルボリンによる窒素のサイクル添加 [3 + 2] サイクル添加/酸素移動/芳香化配列

Da Zhao1, Jiji Zhang1, Zuowei Xie1

  • 1Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The Chinese University of Hong Kong , Shatin, N. T., Hong Kong, Hong Kong, China.

Journal of the American Chemical Society
|October 16, 2015
PubMed
まとめ

研究者らは,ニトロンとオカルボリンとの間の新しい形式の [5 + 2] サイクル添加反応を開発した. この方法は,合成化学を拡張して,カルボラン融合した7つ組の複雑なヘテロサイクルを効率的に合成します.

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