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Updated: Mar 31, 2026

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes

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様々なC−F結合の機能化のためのNi/Cu触媒によるフッ化アルネの脱酸化

Takashi Niwa1, Hidenori Ochiai1, Yasuyoshi Watanabe1

  • 1Chemical Biology Team, Division of Bio-Function Dynamics Imaging, RIKEN Center for Life Science Technologies, 6-7-3 Minatojima-minamimachi, Chuo-ku, Kobe 650-0047, Japan.

Journal of the American Chemical Society
|October 22, 2015
PubMed
まとめ

この研究は,ニッケル/銅の触媒を用いて,フッ素アレンを有価なアリルボロン酸ピナコールエステルに変換するための新しい方法を示しています. このブレークスルーにより,フッ素アレンから様々な機能化されたアレンを2段階の簡潔な合成が可能になる.

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