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Updated: Mar 31, 2026

Synthesis of Information-bearing Peptoids and their Sequence-directed Dynamic Covalent Self-assembly
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Synthesis of Information-bearing Peptoids and their Sequence-directed Dynamic Covalent Self-assembly

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スタッキングインタラクションは,ピレネベースのM ((II) 4L6アーキテクチャの選択的自己組み立てと自己分類を駆動する

Tanya K Ronson1, Derrick A Roberts1, Samuel P Black1

  • 1Department of Chemistry, University of Cambridge , Lensfield Road, Cambridge, CB2 1EW, U.K.

Journal of the American Chemical Society
|October 29, 2015
PubMed
まとめ

研究者はピレンベースのリガンドと金属イオンを使用して金属有機自己組み立てを調査した. 彼らは新しい超分子構造を発見し ピ-スタッキングとドナー-受容体の相互作用を通じて 選択的にゲストを結合するケージも含まれています

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Cycloaddition Reactions: MO Requirements for Thermal Activation

Thermal cycloadditions are reactions where the source of activation energy needed to initiate the reaction is provided in the form of heat. A typical example of a thermally-allowed cycloaddition is the Diels–Alder reaction, which is a [4 + 2] cycloaddition. In contrast, a [2 + 2] cycloaddition is thermally forbidden.
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