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Updated: Mar 30, 2026

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
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ゲルベト工法によるエタノールからn-ブタノールの高度選択的形成:タンデム触媒的アプローチ

Sumit Chakraborty1, Paige E Piszel1, Cassandra E Hayes1,2

  • 1Department of Chemistry, University of Rochester , Rochester, New York 14627, United States.

Journal of the American Chemical Society
|November 4, 2015
PubMed
まとめ

イリジウムと大量のニッケルや銅の水酸化物を使ってエタノールをn-ブタノールに効率的に変換する新しいタンデム触媒システムです. このGuerbetプロセスの革新は,エタノール変換の強化のために低温操作を可能にします.

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The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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