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Updated: Mar 30, 2026

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
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Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles

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D-Aサイクロプロパンの非対称なH2O核性環開き:触媒は水源として機能する

Qi-Kai Kang1, Lijia Wang1, Qiong-Jie Liu1

  • 1State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , Shanghai 200032, China.

Journal of the American Chemical Society
|November 6, 2015
PubMed
まとめ

研究者は水を用いたサイクロプロパンの最初の触媒的エナチオセレクティブリング開封を開発しました. 銅の触媒を用いたこの効率的な方法は,温和な条件下で高いエナチオ選択性を持つ価値ある γ 置換 GBH 誘導体を生成します.

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