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Updated: Mar 30, 2026

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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1-C-アリレートモノカルバ・クロソ・ドデカボレートアニオンにおける σ-とπ-アロマチック性の結合

Mai Otsuka1, Ryo Takita2, Junichiro Kanazawa1

  • 1Graduate School of Pharmaceutical Sciences, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

Journal of the American Chemical Society
|November 21, 2015
PubMed
まとめ

研究者らは,カルボラン誘導体における芳香基間の電子結合を発見した. ベンゼンリングの置換物はヨウ素反応速度に影響を与え,これらのボロンクラスターで重要な共鳴効果を明らかにした.

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An allyl group is a three-carbon conjugated system where the sp³-hybridized allylic carbon is bonded to a CH=CH2 group via a single bond. Allyl anions can be obtained by treating propene with a strong base that can deprotonate methyl groups. Allyl cations are formed as intermediates during substitution reactions involving allylic halides. In both cases, the hybridization of the allylic carbon changes from sp3 to sp2, giving rise to a carbon chain with three sp2-hybridized carbons, each with...
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