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Updated: Mar 29, 2026

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ハパリンドール/アンビギン生物生成はコップ再配置,C-C結合形成カスケードによって媒介される

Shasha Li, Andrew N Lowell, Fengan Yu

  • 1Department of Chemistry, Colorado State University , Fort Collins, Colorado 80523, United States.

Journal of the American Chemical Society
|December 3, 2015
PubMed
まとめ

研究者達は ハパリンドールという 複雑なインドールアルカリドの 生体合成経路を発見しました 鍵となる酵素であるFamD2とFamC1は,特定の前体からコアリング構造を組み立てます.

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The Cope rearrangement is classified as a [3,3] sigmatropic shift in 1,5-dienes, leading to a more stable, isomeric 1,5-diene. The reaction involves a concerted movement of six electrons, four from two π bonds and two from a σ bond, via an energetically favorable chair-like transition state.
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Compounds bearing two hydroxyl groups are known as diols. When the hydroxyl groups are located on adjacent carbon atoms, the diols are called vicinal diols or glycols. Under acidic conditions, vicinal diols undergo a specific reaction called pinacol rearrangement.
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