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Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
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ラジカルテンプレーションと環閉メタテシスの組み合わせによる連鎖

Ian C Gibbs-Hall1, Nicolaas A Vermeulen1, Edward J Dale1

  • 1Department of Chemistry, Northwestern University , 2145 Sheridan Road, Evanston, Illinois 60208-3113, United States.

Journal of the American Chemical Society
|December 15, 2015
PubMed
まとめ

研究者は,分子認識と環閉メタテシスを用いて,電気化学的にアドレッシブルな [2]カテナンを合成した. この新しい機械的に相互接続された分子は酸化時に独特の形状の変化を示し,高い二重選択性を示しています.

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