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Synthesis of a Borylated Ibuprofen Derivative Through Suzuki Cross-Coupling and Alkene Boracarboxylation Reactions
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コバルト触媒ベンジルボリレーション:遠隔の非活性化C ((sp ((3)) -H結合のポリボリレーションと機能化を可能にする

W Neil Palmer1, Jennifer V Obligacion1, Iraklis Pappas1

  • 1Department of Chemistry, Princeton University , Princeton, New Jersey 08544, United States.

Journal of the American Chemical Society
|December 30, 2015
PubMed
まとめ

コバルト複合体は,ビス・ピナコラット・ディボロンを使用してアルキルアレンをC ((sp)) -Hボリル化する. この方法は,ポリボリレーションを達成し,アルキルイソメリゼーションとの結合活性化によって遠隔C-H結合を機能化します.

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