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Updated: Mar 28, 2026

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
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Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators

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バイシナル・ダイアミン誘導アルドル反応の移行状態

Adam Simon1, Yu-Hong Lam1, K N Houk1

  • 1Department of Chemistry and Biochemistry, University of California, Los Angeles , 607 Charles E. Young Drive East, Los Angeles, California 90095-1569, United States.

Journal of the American Chemical Society
|January 5, 2016
PubMed
まとめ

密度関数計算では,近隣のダイアミン触媒アルドール反応が周期的移行状態を好むことが明らかである. この9つの環の構造,特に冠の形状は,これらの化学反応で観察されたステレオ選択性を説明します.

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