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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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エンドオヘドラルメタロフルレンのケージトポロジーを予測する主要な構造モチーフ

Yang Wang1,2, Sergio Díaz-Tendero1,3, Fernando Martín1,2,3

  • 1Departamento de Química, Módulo 13, Universidad Autónoma de Madrid , 28049 Madrid, Spain.

Journal of the American Chemical Society
|January 15, 2016
PubMed
まとめ

フラーレンアニオンの安定性は,複雑な計算ではなく,単純な構造モチーフによって決定されます. これらのモチーフを数えると,相対的なエネルギーが予測され,エンドヘッダルのメタロフルレンのケージ構造が説明されます.

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