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Updated: Mar 26, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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1,3-ダイエネとディアゾエステルの間の前例のない内分子 [4 + 2] - サイクル添加

Huang Qiu1,2,3, Harathi D Srinivas1, Peter Y Zavalij2

  • 1Department of Chemistry, The University of Texas at San Antonio , San Antonio, Texas 78249, United States.

Journal of the American Chemical Society
|January 23, 2016
PubMed
まとめ

この研究は,ダイアゾ化合物とダイエンを用いた新しい [4 + 2] - サイクル添加反応を導入する. このプロセスは,金 (I) 触媒による再配置によって開始され,高収量で穏やかな条件下で発生します.

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