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Updated: Mar 26, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

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二次リドックス活性エステルのNi-触媒化アリル-アルキルクロスカップリング

Josep Cornella1, Jacob T Edwards1, Tian Qin1

  • 1Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

Journal of the American Chemical Society
|February 3, 2016
PubMed
まとめ

化学者は,アルキルカルボキシル酸とアリル亜鉛の反応剤を,アルキルハリドの代用として新しい酸化還元活性エステルを使用して簡単にカップリングすることができます. この実用的なニッケル触媒による変換は,有機合成の費用対効果が高く,広く適用可能な方法を提供します.

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