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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs

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メカニカル・ポイント・キラル・ロタキサンによる非対称な触媒

Yusuf Cakmak1, Sundus Erbas-Cakmak1, David A Leigh1

  • 1School of Chemistry, University of Manchester , Oxford Road, Manchester M13 9PL, United Kingdom.

Journal of the American Chemical Society
|February 3, 2016
PubMed
まとめ

ロタキサンにおける機械的点キラリティは,非対称な触媒を可能にします. このメカノキロゲネシスアプローチは,エナミンとイミニウム活性化経路を通じて,エナチオセレクティブの有機触媒作用を提供します.

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