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Updated: Mar 25, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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固体状態の反応性ドナー/受容体およびドナー/ドナーロジウムカルベンの構造とその触媒への影響

Christophe Werlé1, Richard Goddard1, Petra Philipps1

  • 1Max-Planck-Institut für Kohlenforschung , D-45470 Mülheim/Ruhr, Germany.

Journal of the American Chemical Society
|February 25, 2016
PubMed
まとめ

炭酸ロジウムの中間物質は,以前は研究には過度に反応的であったが,現在ではX線構造と光譜を用いて特徴づけられている. この研究は,その構造を明らかにし,ロジウム触媒反応におけるステレオ選択性に影響を与える.

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