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Updated: Mar 25, 2026

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

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ドナーで安定したシラサイクロブタノン:室温でのレトロ[2 + 2]サイクル添加反応による1-シラケテンの前駆体

Thibault Troadec1, Morelia Lopez Reyes1, Ricardo Rodriguez1

  • 1Université de Toulouse , UPS, and CNRS, LHFA UMR 5069, F-31062 Toulouse, France.

Journal of the American Chemical Society
|February 27, 2016
PubMed
まとめ

研究者は,シラクロプロピリデンとベンザルデヒドの反応により,ドナーで安定したシラクロブタノンを合成した. この化合物は室温でレトロ- [2 + 2] - サイクル添加を経て,新しいNHC-安定した1-シラケテンとシス-スティルベンを得ます.

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