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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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四次炭素ステレオセンターの構築のための直接触媒非対称マニッヒ反応

Barry M Trost1, Tanguy Saget1, Chao-I Joey Hung1

  • 1Department of Chemistry, Stanford University , Stanford, California 94305-5080, United States.

Journal of the American Chemical Society
|March 9, 2016
PubMed
まとめ

この研究は,複雑な分子を作るための新しい触媒的方法を導入します. 亜鉛プロフェノール触媒は,アルファ分岐ケトンを用いて四次炭素ステレオセンターの効率的な合成を可能にします.

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