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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

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構造的に多様なダイアザフローレン結合パラジウム ((II) コンプレックスと,その影響によるエアロビック酸化反応

Paul B White1, Jonathan N Jaworski1, Charles G Fry1

  • 1Department of Chemistry, University of Wisconsin-Madison , 1101 University Avenue, Madison, Wisconsin 53706, United States.

Journal of the American Chemical Society
|March 12, 2016
PubMed
まとめ

リガンド4,5-ディアザフローレン-9-オン (DAF) は,パラジウムとの調整モード間で急速にシフトし,Pd触媒化酸化反応における有効性を説明する.

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Arenediazonium substitution reactions occur when the diazonium group is substituted by various functional groups such as halides, hydroxyl, nitrile, etc. For instance, arenediazonium salts react with copper(I) salts of chloride, bromide, or cyanide to form corresponding aryl chlorides, bromides, and nitriles. These reactions are named Sandmeyer reactions. Although the mechanism of this reaction is complicated, as illustrated in Figure 1, they are believed to progress via an aryl copper...
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