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Characterizing Lewis Pairs Using Titration Coupled with In Situ Infrared Spectroscopy
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挫折したルイス対のルイス基本成分としての移行金属オックス

Nikola S Lambic1, Roger D Sommer1, Elon A Ison1

  • 1Department of Chemistry, North Carolina State University , 2620 Yarbrough Drive, Raleigh, North Carolina 27695-8204, United States.

Journal of the American Chemical Society
|March 23, 2016
PubMed
まとめ

ダイミドピリジン (DAP) リガンドとB ((C6F5) 3) の新しいオクソレニウム複合体は,オレフィン水素化を触媒化するアダクトを形成する. この挫折したルイス・ペアのアプローチは 触媒活性が強化されたことを示している.

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