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A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis
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A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis

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表面脱水性アリル-アリル結合形成に対する反応性および地域選択性の制御

Nemanja Kocić1, Xunshan Liu2, Songjie Chen2

  • 1Institute of Experimental and Applied Physics, University of Regensburg , 93053 Regensburg, Germany.

Journal of the American Chemical Society
|April 10, 2016
PubMed
まとめ

金属表面では,化学合成における地域選択性は,原子力顕微鏡 (AFM) とスキャニングトンネル顕微鏡 (STM) を使用して実証される. 研究者は,ピラジノ[2,3-f][4,7]フェナントロリン (pap) の選択的アリル結合を金に達成し,ピラジンリングの好ましいC-H活性化を明らかにした.

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