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A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
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パラジアム/l-プロリン触媒によるエナンチオセレクティブ α-アリラティブ・デシンメトリゼーション

Ren-Rong Liu1, Bao-Le Li1, Jun Lu1

  • 1College of Chemical Engineering, Zhejiang University of Technology , Hangzhou 310014, China.

Journal of the American Chemical Society
|April 15, 2016
PubMed
まとめ

新しいパラジアム/l-プロリン触媒は,サイクロヘクサノンの高度にエナンチオセレクティブなα-アリレーションを可能にします. この方法は,有価なα-カルボニル三次性ステレオセンターを持つ光学的に活性なモルファン誘導体を効率的に生成します.

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