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Synthesis of a Borylated Ibuprofen Derivative Through Suzuki Cross-Coupling and Alkene Boracarboxylation Reactions
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テトラアリル二ボランの制御された還元によるB-B結合の形成 ((6)

Thomas Kaese1, Alexander Hübner1, Michael Bolte1

  • 1Institut für Anorganische und Analytische Chemie, Goethe-Universität Frankfurt , Max-von-Laue-Straße 7, D-60438 Frankfurt am Main, Germany.

Journal of the American Chemical Society
|April 26, 2016
PubMed
まとめ

ディメリック・アリル (hydro) ボランは,ボロン添加グラフェンの前駆体として機能する. LiNaph/THFまたはKC8のような反応剤との還元結合は,リング収縮型および水素ブリッジ型を含む様々なボロン含有構造を生成する.

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