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Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
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Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes

Published on: April 1, 2013

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シドノーン-アルキーン・サイクロアディションによる完全芳香性高性能セモセット

Nisha V Handa, Shaoguang Li, Jeffrey A Gerbec1

  • 1Mitsubishi Chemical USA, Inc. , Chesapeake, Virginia 23320, United States.

Journal of the American Chemical Society
|May 17, 2016
PubMed
まとめ

研究者らは1,3二極サイクロアディション反応を用いて,高性能な新型サーモセットを作成した. これらの高度な材料は 特殊な耐熱性があり 厳しい用途に適しています

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Thermal cycloadditions are reactions where the source of activation energy needed to initiate the reaction is provided in the form of heat. A typical example of a thermally-allowed cycloaddition is the Diels–Alder reaction, which is a [4 + 2] cycloaddition. In contrast, a [2 + 2] cycloaddition is thermally forbidden.
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