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Updated: Mar 20, 2026

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

Published on: May 21, 2019

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銅イオンに結合したペロクソとスーペロクソモエリティー:小さな再編成エネルギーを持つ電子移転均衡

Rui Cao1, Claudio Saracini1,2, Jake W Ginsbach3

  • 1Department of Chemistry, Johns Hopkins University , Baltimore, Maryland 21218, United States.

Journal of the American Chemical Society
|May 27, 2016
PubMed
まとめ

この研究は,二銅複合体の酸化を詳細に説明し,逆転的に過酸化に還元できるスーパーオキソ種を形成します. この研究で,これらの銅と酸素の電子移転メカニズムと再酸化ポテンシャルが解明されました.

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