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Achieving Moderate Pressures in Sealed Vessels Using Dry Ice As a Solid CO2 Source
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活性化されていないアルキル塩素をCO2でNi触媒カルボキシル化

Marino Börjesson1, Toni Moragas1, Ruben Martin1,2

  • 1Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology , Av. Països Catalans 16, 43007 Tarragona, Spain.

Journal of the American Chemical Society
|June 9, 2016
PubMed
まとめ

この研究では,大気圧で二酸化炭素 (CO2) を使用したアルキル塩化物の新しい触媒カルボキシル化法が導入されています. この突破は,活性化されていないアルキル塩化物の最初の分子間クロスエレクトロフィール結合を可能にし,クロスカップリング化学を前進させました.

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