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Updated: Mar 19, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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分子内ベンゾイン反応によるダイナミック・キネティック解像度:合成応用と機械的洞察

Guoxiang Zhang1, Shuang Yang1, Xiaoyan Zhang1

  • 1State Key Laboratory of Structural Chemistry and ‡Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences , Fuzhou, Fujian 350002, PR China.

Journal of the American Chemical Society
|June 9, 2016
PubMed
まとめ

チラルのN-ヘテロサイクルカルベンの触媒は,ケトエスターとダイケトンの高度に選択的な動的運動分解を可能にします. この方法は,正確なステレオ化学制御で機能化されたテトラロン誘導体を効率的に生成します.

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