鉄の代わりに貴金属を含む人工ヘムタンパク質によるアビオロジック触媒

Hanna M Key1,2, Paweł Dydio1,2, Douglas S Clark3,4

  • 1Department of Chemistry, University of California, Berkeley, California 94720, USA.

Nature
|June 15, 2016
PubMed
まとめ

研究者たちは タンパク質に含まれる鉄を イリジウムのような高貴金属に置き換えて 新しい人工酵素を作り出しました これらのエンジニアリングされた金属酵素は,C-H結合機能化と選択性サイクロプロパネーションを含む新しい化学反応を触媒化し,アビオロジカル触媒の可能性を拡大します.

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