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Updated: Mar 19, 2026

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
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イリジウムのPOCOP型ピンチャー複合体によって触媒化された高ターンオーバー芳香C-Hボリレーション

Loren P Press1, Alex J Kosanovich1, Billy J McCulloch1

  • 1Department of Chemistry, Texas A&M University , College Station, Texas 77842, United States.

Journal of the American Chemical Society
|June 22, 2016
PubMed
まとめ

この研究は,POCOPピンサー複合体を用いて,アーレンのIr-触媒化C-Hボリレーションを証明し,高い周回率を達成しました. イリジウムを活性化するために,他のボリル化方法とは対照的に,触媒サイクルには犠牲オレフィンが必要です.

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