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Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI
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Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI

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シングレット (Phosphino) フォスフィニデンは電性である

Max M Hansmann1, Rodolphe Jazzar1, Guy Bertrand1

  • 1UCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California, San Diego , La Jolla, California 92093-0358, United States.

Journal of the American Chemical Society
|June 25, 2016
PubMed
まとめ

室温に安定したフォスフィニデンは電子欠乏性であり,一酸化炭素,カルベン,フォスフィンと反応する. 電子計算が反対を示唆しているにもかかわらず,彼らの反応性は,彼らの電愛性性質を確認します.

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