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Updated: Mar 17, 2026

Chemoselective Modification of Viral Surfaces via Bioorthogonal Click Chemistry
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終端アルキンの表面光化学的ホモカップリング

Luciano Colazzo1,2, Francesco Sedona1, Alessandro Moretto1

  • 1Dipartimento di Scienze Chimiche, Università di Padova , Via Marzolo 1, 35131 Padova, Italy.

Journal of the American Chemical Society
|July 21, 2016
PubMed
まとめ

研究者は,アリル-アルキンホモカップリングのための光誘導の金属フリー方法を開発しました. この光化学プロセスは,金属誘発の副作用を回避して,新しい機能的材料のためのオーダーされたブタジニル誘導体を効率的に生成します.

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Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
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Introduction
One of the convenient methods for the preparation of aldehydes and ketones is via hydration of alkynes. Hydroboration-oxidation of alkynes is an indirect hydration reaction in which an alkyne is treated with borane followed by oxidation with alkaline peroxide to form an enol that rapidly converts into an aldehyde or a ketone. Terminal alkynes form aldehydes, whereas internal alkynes give ketones as the final product.
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