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機械的に活性化されたシス・トゥ・トランス・サイクロプロパン・イソメリゼーションの単分子観察

Junpeng Wang1, Tatiana B Kouznetsova1, Stephen L Craig1

  • 1Department of Chemistry, Duke University , Durham, North Carolina 27708, United States.

Journal of the American Chemical Society
|August 9, 2016
PubMed
まとめ

トロウエンのシス-ジェム-ディフローロcyclopropaneポリマーの機械化学的活性化は2つの力移行を示しています. これらのトランジションは,メチルベンゾアートの振る舞いとは異なり,トランス同位体への同位化を含む競合する反応を示します.

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