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Updated: Mar 16, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

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経路に依存したアントラセーンエッジM ((II) 4L6テトラヘッドの改造

Tanya K Ronson1, Ben S Pilgrim1, Jonathan R Nitschke1

  • 1Department of Chemistry, University of Cambridge , Lensfield Road, Cambridge CB2 1EW, U.K.

Journal of the American Chemical Society
|August 9, 2016
PubMed
まとめ

Fe(II) 4L6四面体ケージの組み立て後の改変は,ダイエルス-アルダー反応を用いて新しい結合部位を生成する. この超分子宿主改変により,フルレンとアニオン客の選択的封じ込めが可能になり,調節可能な宿主-客の化学反応が示される.

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