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Updated: Mar 16, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

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(η(4) -ブタジーン) Sn(0) コンプレックス: 4π電子ドナーとしてブタジーンを使用するゼロバルントpブロックエレメントのための新しいアプローチ

Takuya Kuwabara1, Marisa Nakada1, Jumpei Hamada1

  • 1Department of Chemistry, Graduate School of Science and Engineering, Saitama University , Shimo-okubo, Sakura-ku, Saitama 338-8570, Japan.

Journal of the American Chemical Society
|August 12, 2016
PubMed
まとめ

研究者らは4π電子ドナーとしてブタディエンを用いて,ゼロバレントグループ14の元素を安定させる新しい方法を開発した. このアプローチは これらのユニークな元素の 協調化学について 新たな洞察を与えてくれます

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Neutral hydrocarbons like cyclopentadiene with an odd number of carbon atoms and one intervening CH2 group in the ring are not aromatic. Cyclopentadiene with 4 π electrons does not satisfy the 4n + 2 π electron rule. Additionally, the intervening CH2 group is sp3 hybridized and lacks a vacant p orbital, thereby interrupting the overlap of p orbitals in a continuous manner and preventing the delocalization of π electrons throughout the ring.
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