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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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低座標金 (III) センターでのβ-水素除去

Feriel Rekhroukh1, Laura Estevez2,3, Sonia Mallet-Ladeira4

  • 1UPS, Laboratoire Hétérochimie Fondamentale Appliquée, Université de Toulouse and CNRS, LHFA UMR 5069 , 118 route de Narbonne, Toulouse F-31062, France.

Journal of the American Chemical Society
|August 18, 2016
PubMed
まとめ

この研究では,黄金 (III) アルキル複合体がβ-水素除去を受け,オレフィンを形成することを明らかにした. チェーンウォーキングメカニズムによるオレフィンイソメリゼーションは,金 (III) 化学で観察された.

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