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Updated: Mar 15, 2026

Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions
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Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions

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溶媒水素結合によるヘテロサイクルのアザディエンのサイクル添加反応の触媒:メトキサチンの簡潔な総合成

Christopher M Glinkerman1, Dale L Boger1

  • 1Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

Journal of the American Chemical Society
|August 30, 2016
PubMed
まとめ

この研究は,HFIPやTFEのようなパーフルオロアルコールを用いた反転電子需要ダイエルス-アルダー反応の一般的触媒法を導入している. このアプローチは,ヘテロサイクルのアザディエンを活性化し,効率的なサイクロアディション反応を可能にします.

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