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Updated: Mar 15, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

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リガンド交換媒介による活性化と塩化アルミナによるリベースオレフィン転化触媒の安定化

Alessandro Gallo, Anthony Fong, Kai C Szeto1

  • 1Laboratoire de Chimie, Catalyse, Polymères et Procédés, UMR 5265 CNRS/ESCPE-Lyon/UCBL, ESCPE Lyon, F-308-43, Boulevard du 11 Novembre 1918, F-69616 Villeurbanne Cedex, France.

Journal of the American Chemical Society
|August 31, 2016
PubMed
まとめ

アルミニウム (Al2O3) の広範な塩化により,高度に活性なルイス酸性サイトが生成される. この改変により,メチルトリオキソルヘニウム (MTO) のオレフィン転化剤の性能が著しく向上し,活性と安定性が向上する.

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Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
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