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熱メタンをRh1-ドープされた酸化アルミニウムのクラスターカチオンRhAl3O4によってシンガスに変換する

Ya-Ke Li1,2, Zhen Yuan1,2, Yan-Xia Zhao1

  • 1Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190, P. R. China.

Journal of the American Chemical Society
|September 9, 2016
PubMed
まとめ

この研究は,RhAl3O4+クラスターがメタンを重要な化学的中間体であるシンガスに変換できることを示しています. ロジウム原子は活性部位であり,C−H結合の活性化によってメタン変換を推進する.

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