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フェニリオジン二酸化物における酸活性化:直接観察,構造,および影響

Susana Izquierdo1, Stéphanie Essafi2, Iker Del Rosal2

  • 1Institute of Chemical Research of Catalonia (ICIQ), Barcelona Institute of Science and Technology , 43007, Tarragona, Spain.

Journal of the American Chemical Society
|September 9, 2016
PubMed
まとめ

有機合成に不可欠な高価ヨウ素反応剤は,酸によって活性化されます. この研究は,PhI (OAc) 2とBF3·Et2Oを用いてこの活性化のメカニズムを解明し,強化反応性に関する構造的および電子的洞察を示しています.

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