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Updated: Mar 15, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

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挫折したルイス・ペア アモニア・ボランを用いたイミンのアシンメトリック・トランスファー・水素化

Songlei Li1,2, Gen Li1,2, Wei Meng1,2

  • 1Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190, China.

Journal of the American Chemical Society
|September 9, 2016
PubMed
まとめ

研究者は,金属のない非対称的な転送水素化のための新しい挫折したルイスペア (FLP) を開発した. この触媒システムは,アンモニア・ボランを水素源として使って,イミンから光学的に活性なアミンを効率的に生成します.

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Imines are formed under mildly acidic conditions. A pH of 4.5 is ideal for the reaction.
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